Synergism between copper and silver nanoclusters induces fascinating structural modifications, properties, and applications.

Abstract

Among the group 11 transition metal elements, Cu and Ag are widely studied due to their cost effectiveness and easy availability. However, the synergism between copper and silver is also very promising, exhibiting intriguing structures, properties, and applications. Nanoclusters, which are missing links between atoms and nanoparticles, are highly fluorescent due to their discrete energy levels. Their fluorescence can be efficiently tuned because of the synergistic behaviour of copper and silver. Furthermore, their fluorescence can be selectively altered in the presence of various analytes and sensing platforms, as reported by various groups. Moreover, copper clusters can be utilized for sensing silver while silver nanoclusters can be utilized for sensing ionic copper due to the strong interaction between copper and silver. Furthermore, DFT studies have been performed to understand the structural modification due to CuAg synergism. A concise summary of the synergism between copper and silver can open a new window of research for young scientists venturing into the field of environmental nanoscience.