Abstract
The distribution equilibria of cobalt(II) with 4-methyl- N-8-quinolinylbenzene sulphonamide in the presence of tributylphosphate or trioctylphosphine oxide dissolved in toluene were studied as a function of hydrogen ion concentration and the concentration of the organophosphorus compounds. Evaluation of the extraction data made it possible to deduce the stoichiometry of the extracted species, determine their corresponding extraction constants and quantify the synergic effect.
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