Synergetic Improvement in Thermal Conductivity and Flame Retardancy of Epoxy/Silver Nanowires Composites by Incorporating "Branch-Like" Flame-Retardant Functionalized Graphene.

Abstract

The significant fire hazards on the polymer-based thermal interface materials (TIM) used in electronic devices are but often neglected. Also, high filler loading with the incident deterioration of mechanical, thermal, and processing properties limits the further application of the traditional polymer-based TIMs. In this work, a ternary TIMs with epoxy resin (EP) matrix, silver nanowires (AgNWs), and a small amount of flame-retardant functionalized graphene (GP-DOPO) were proposed to address the above questions. Briefly, a facile "branch-like" strategy with a polymer as the backbone and flame-retardant molecule as the branch was first used to functionalize reduced graphene oxide (RGO) toward increasing the flame-retardant grafting ratio and RGO's compatibility in matrix, and the resulted GP-DOPO was then in situ introduced into the EP/AgNW composites. As expected, the incorporation of GP-DOPO (2 wt %) can increase the thermal conductivity to 1.413 W/(m K) at a very low AgNW loading (4 vol %), which is 545 and 56% increments compared to pure EP and EP/AgNW, respectively. The prominent improvement in thermal conductivity was put down to the synergetic effect of AgNW and GP-DOPO, i.e., the improving dispersion and bridging effect for AgNWs by adding GP-DOPO. Moreover, the high flame-retardant grafting amount and the excellent compatibility of GP-DOPO resulted in a strong catalytic charring effect on EP matrix, which further formed a robust protective char layer by combining the AgNW and graphene network. Therefore, the flame retardancy of EP/AgNW was significantly improved by introducing GP-DOPO, i.e., the peak heat release rate, total heat release and total smoke production reduced by 27.0, 32.4, and 30.9% reduction compared to EP/AgNW, respectively.