Abstract
The title complex, [TiCl 2 (C 19 H 26 )], belongs to the short-bridged ansa-metallocene family, members of which are useful in polymerization processes. It was obtained in a three-step reaction sequence from 2,2-bis(cyclopentadienyl)propane in moderate overall yield. The most important structural feature is the distortion in the angles caused by the short bridge ; the two isopropyl groups do not contribute significantly to the intramolecular tension in the molecule.
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