Abstract

Data on the Raman scattering of F and F+ centres in CaO are recorded. Symmetry assignments of the Raman effect of F+ centres are in agreement with the F+ emission spectrum measurements of Hughes, Pells and Sender. Furthermore, polarization results show that the frequency separation between T2g and Eg modes is about 17 cm-1. The vibrational modes of F centres are also discussed.

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