Abstract
A convenient synthetic approach to build up new polynucleating ligands is presented. Symmetric and asymmetric pyridylpyrimidine dimers are produced by radical anion coupling and nucleophilic addition, respectively. A diruthenium complex of the asymmetric ligand was synthesised and characterised by cyclic voltammetry, luminescence and 99Ru NMR spectroscopy. (© Wiley-VCH Verlag GmbH, 69451 Weinheim, Germany, 2002)
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