Switching nanoscale temperature fields with high-order plasmonic modes in transition metal nanorods.

Abstract

Depending on the photoirradiation conditions, metal nanostructures exhibit various plasmonic modes, including dipolar, quadrupolar, and hexapolar modes. This work demonstrates numerically that these high-order plasmonic modes can be used to switch nanoscale temperature distributions during the plasmonic heating of a manganese (Mn) nanorod. The key feature of Mn is its low thermal conductivity. Generally, when noble metal nanostructures are used for plasmonic heating, the nanostructure surface will be almost isothermal regardless of the order of the excited plasmonic modes because of the high thermal conductivity of noble metals, e.g., the thermal conductivity of gold is 314 W m-1 K-1. However, unlike noble metals, Mn has a significantly lower thermal conductivity of 7.8 W m-1 K-1. Due to this lower thermal conductivity, the distinct spatial characteristics of the high-order plasmonic modes can be transcribed clearly into nanoscale temperature fields, which are achieved by generating polarization currents by high-order plasmons within the nanorod. These findings strongly suggest that high-order plasmonic modes hold significant potential for the advanced and precise manipulation of heat generation at the nanometer scale in thermoplasmonics.