Abstract
Use of CO2 to realize both swelling and deswelling in a same type of copolymer is a challenging topic. Herein, we synthesized poly(acrylamide-co-2-dimethylaminoethyl methacrylate) (P(AM-co-DMAEMA)) copolymer hydrogels by easy solution copolymerization that showed both swelling and deswelling when exposed to CO2. Interestingly, the copolymer hydrogels were found to show a convincing CO2-induced “composition-dependent” swelling behaviors. The as-prepared hydrogels with 4.1 to 23.3 mol% DMAEMA showed a decreased swelling ratio when CO2 was purged. In contrast, further raising DMAEMA molar ratio from 23.3 to 67.8%, the copolymer hydrogels showed CO2-induced increased swelling. Insights from NMR and XPS results revealed different characteristics of poly(N,N-dimethylaminoethyl methacrylate in the hydrogel samples with varying monomer compositions, which were considered to be responsible for the composition-dependent swelling behavior. By discovering a simple method to synthesize a copolymer hydrogel which showed CO2-induced composition-dependent swelling behaviors, this study is conducive to developing CO2-tunable smart materials.
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