Abstract
The development of large, multifunctional structures from sustainable wood nanomaterials is challenging. The need to improve mechanical performance, reduce moisture sensitivity, and add new functionalities, provides motivation for nanostructural tailoring. Although existing wood composites are commercially successful, materials development has not targeted nano-structural control of the wood cell wall, which could extend the property range. For sustainable development, non-toxic reactants, green chemistry and processing, lowered cumulative energy requirements, and lowered CO2-emissions are important targets. Here, modified wood substrates in the form of veneer are suggested as nanomaterial components for large, load-bearing structures. Examples include polymerization of bio-based monomers inside the cell wall, green chemistry wood modification, and addition of functional inorganic nanoparticles inside the cell wall. The perspective aims to describe bio-based polymers and green processing concepts for this purpose, along with wood nanoscience challenges.
Highlights
Bio-based materials are essential for a future sustainable society
The resulting biocomposite product is a good candidate for sustainable wood nanotechnology
Sustainable wood nanotechnologies for wood composites are interesting for infrastructure applications
Summary
Bio-based materials are essential for a future sustainable society. With about three trillion trees on earth, wood is one of the most abundant renewable and sustainable material (Crowther et al, 2015). For random-inplane CNF orientation and 50 vol% CNF, the modulus can approach 10 GPa and the strength exceed 150 MPa. The high energy demand, for extracting nanocellulose from the wood pulp fiber cell wall, combined with numerous composite preparation steps (CNF filtering, controlled drying, thermoset precursor impregnation, prepreg stacking and elevated temperature molding), and lack of recycling methods constitute major obstacles to the sustainability of CNF biocomposites. The fully bio-based transparent wood biocomposites showed improved optical and mechanical properties, due to high polymer modulus and excellent matching of the refractive index of cellulose (Montanari et al, 2021). The resulting biocomposite product is a good candidate for sustainable wood nanotechnology
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