Sustainable water decontamination in a fluidic sequential electrochemical reactor

Abstract

Here, we demonstrate an integrated fluidic sequential electrochemical system for effective water decontamination. The system consists of a Ti mesh anode deposited with nanoscale IrO2 and a CNT filter functionalized with nanoconfined Fe2O3. By conducting anodic oxygen evolution reaction (OER) and 2e– oxygen reduction reaction (ORR) sequential electrolysis, our system enables sustainable O2 generation at the anode, followed by transformation of O2 into H2O2 at the cathode, which then led to the production of 1O2 in the presence of nanoconfined Fe2O3. No chemical inputs were needed nor side products occurred during the whole sequential electrochemical processes. The effectiveness of the system was evaluated using tetracycline as a model emerging contaminant. Recirculating at 3 mL min–1, the system exhibited negligible iron and iridium leaching (≤0.01 mg L–1) and high tetracycline degradation efficiency (≥95%). Such excellent efficacy can be maintained across a wide pH range and in complicated water matrices.