Sustainable removal of hexavalent chromium using graphene oxide - Iron oxide reinforced pectin/polyvinyl alcohol magnetic gel beads

Abstract

The study investigated removal of hexavalent chromium Cr (VI) from aqueous solution using graphene oxide‑iron oxide reinforced pectin/polyvinyl alcohol magnetic gel beads prepared through co-precipitation and freeze-drying technique. Scanning electron microscopy, X-ray photoelectron spectroscopy, Fourier-transform infrared spectroscopy, X-ray diffraction, vibrating sample magnetometer, N2 adsorption-desorption isotherm, and zeta potential are used for characterization. The surface area of magnetic gel beads calculated by BET method was determined to be 100.95 m2/g, significantly higher than that of GO and GO-Fe3O4. The optimum removal efficiency of GO-Fe3O4/Pec/PVA was assessed by batch method at variables such as pH(1–6), adsorption time(0–180 min), and temperature(25–35 °C). Accordingly, 0.2 g GO-Fe3O4/Pec/PVA dose, pH 2, contact time: 120 min at 25 °C were found to be the optimal conditions, and maximum adsorption capacity of GO, GO-Fe3O4 and GO-Fe3O4/Pec/PVA toward Cr(VI) removal was found to be 39.5, 62.5 and 78.55 mg g−1, respectively. Kinetic and isotherm studies indicate adsorption data follow pseudo-second-order kinetic and Langmuir isotherm models. Thermodynamic studies showed adsorption capacities of adsorbents decreased when temperature increased which indicated adsorption for Cr (VI) was an exothermic process. The activation energies were found to be 34.92, 26.57, and 35.23 KJ mol−1 for GO, GO-Fe3O4, and GO-Fe3O4/Pec/PVA, respectively, which illustrated adsorption of Cr(VI) onto the surface of adsorbents was a physical process. The beads exhibit excellent recoverability and reusability over five cycles. Overall, GO-Fe3O4/Pec/PVA demonstrates exceptional adsorption properties and can serve as an efficient, stable, less toxic, and magnetically separable adsorbent for removal of Cr(VI) from aqueous solution.