Sustainable paper coating with enhanced barrier properties based on esterified lignin and PBAT blend

Abstract

Sustainable and biodegradable packaging materials are appealing alternatives to the petrochemical-derived and non-biodegradable plastics that currently dominate the market. However, their inferior barrier properties and high cost inhibit their widespread applications. In this work, pristine and esterified lignin were investigated as a functional filler of poly (butylene adipate-co-terephthalate) (PBAT) based bioplastic paper coating formulations. For this, the pristine and esterified lignin (10–50 wt%) were separately dispersed in a solvent and incorporated in PBAT solutions and applied on paper substrates. The effects of varying concentrations of pristine and esterified lignin on the rheology, mechanical, morphology, and barrier properties of the coated paper substrate were investigated. Comprehensive characterization of esterified lignin/PBAT coatings exhibited enhanced dispersion of the lignin fraction in the PBAT, resulting in excellent wet tensile properties and enhanced water, oil, and oxygen barrier performance. Overall, the studied coating formulations have appealing properties for food contact materials, such as paper wraps and paperboard applications, as a sustainable and eco-friendly alternative to the incumbent coating materials, such as petroleum sourced waxes and polyolefin-based coatings.