Sustainable Lignin-Derived Hierarchical Porous Carbon for Supercapacitors: A Novel Approach for Holding Electrochemical Attraction Natural Texture Property of Precursor.

Abstract

Finding low-cost and environmentally friendly precursors that can maintain their electrochemical attraction natural texture properties while obtaining hierarchical porous carbons with high electrochemical performance is desirable for offering a leap forward in industrial applications. However, phenomena associated with the high microporosity of porous carbon remain. Herein, the protective effect of hydrothermal methods and the micropore-forming ability of KOH were used. The as-synthesized porous carbon (PC-1) holds the natural texture property (the retention of texture property with apertures higher than 2 nm was up to 80%) and achieves three-dimensional (3D) architecture with hierarchical structures accompanied by an ultrahigh specific surface area (3559.45 m2/g). Benefiting from its texture properties, PC-1 possesses a high specific capacitance of 288.75 F/g at 0.5 A/g, excellent rate capability as high as 223.72 F/g at 10 A/g, and remarkable conductivity in a three-electrode system with a 6 M KOH electrolyte. In view of its environment friendliness, low cost, and excellent specific capacitance, PC-1 has promising applications in high-performance supercapacitors.