Sustainable landfill leachate treatment: Optimize use of guar gum as natural coagulant and floc characterization

Abstract

Sustainable wastewater treatment necessitates the application of natural and green material in the approach. Thus, selecting a natural coagulant in leachate treatment is a crucial step in landfill operation to prevent secondary environmental pollution due to residual inorganic coagulant in treated effluent. Current study investigated the application of guar gum in landfill leachate treatment. Central composite design in response surface methodology was used to optimize the performance of Chemical Oxygen Demand (COD) removal. Quadratic model developed indicated the optimum COD removal 22.57% at guar gum dosage of 44.39 mg/L, pH 8.56 (natural pH of leachate) and mixing speed 79.27 rpm. Scanning electron microscopy showed that floc was compact and energy-dispersive-x-ray analysis showed that guar gum was capable to adsorb multiple ions from the leachate. Structural characterization using Fourier Transform Infrared analysis demonstrated that hydrogen bonding between guar and pollutant particles was involved in coagulation and flocculation process. Therefore, guar gum coagulant present potential to be an alternative in leachate treatment where pH requirement is not required during treatment. Simultaneously, adsorption by guar gum offers added pollutant removal advantage.