Abstract
Converting solid wastes into new materials for wastewater decontamination is a feasible “one stone, three birds” strategy to achieve sustainable value-added utilization of resources and minimize waste emissions, but significant challenges remain. In response to this, we proposed an efficient “mineral gene reconstruction” method to synchronously transform coal gangue (CG) into a green porous silicate adsorbent without using any harmful chemicals (i.e., surfactants, organic solvents). The one of the synthesized adsorbents with a high specific surface area (582.28 m2/g) and multimetallic active centres shows outstanding adsorption performance (adsorption capacities: 168.92 mg/g for Cd(II), 234.19 mg/g for methylene blue (MB); removal rate: 99.04% for Cd(II) and 99.9% for MB). The adsorbent can also reach a high removal rate of 99.05%∼99.46% and 89.23%∼99.32% for MB and Cd(II) in real water samples (i.e., Yangtze River, Yellow River, seawater and tap water), respectively. After 5 adsorption-desorption cycles, the adsorption efficiency remained above 90%. The adsorbents mainly adsorbed Cd(II) by electrostatic attraction, surface complexation and partial ion exchange and MB by electrostatic and hydrogen bonding interactions. This study provides a sustainable and promising platform for developing a new-generation cost-efficient adsorbent from waste for clean water production.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
