Sustainable Green Approach of Silica Nanoparticle Synthesis Using an Agro-waste Rice Husk

Abstract

Agro-waste can provide a non-metallic, environmentally friendly bio-precursor for the production of green silica nanoparticles. To manufacture silica nanoparticles from rice husk, biogenic silica nanoparticles were generated using an alkaline precipitation approach. Rice husk as a source of silica nanoparticles is environmentally and economically valuable because it is a plentiful lower price agricultural derivative that can be used to help with waste management. During the synthesis process, the dose of rice husk ash was used at 5 g at pH 7, alkali dose concentration of 0.5 M, reaction period of 3.5 h, and temperature of 90°C that produced maximum silica nanoparticles with a yield of 88.5%. To optimize the silica nanoparticle production from rice husk ash Box Behnken Design (BBD) a subcategory of the response surface methodology (RSM) was accomplished. BBD model was successfully matched, as evidenced by the high correlation values of adjusted R2 0.9989 and predicted R2 0.9977. Silica nanoparticles’ amorphous form generated from rice husk ash is indicated by XRD analysis 2Ө peak at 22.12° and UV-Vis Spectroscopy absorbance peak at 312 nm. The amorphous shape of silica is amorphous and crystalline defined through XRD. nanoparticles generated from rice husk ash is indicated by FESEM analysis and EDX analysis, confirming that the SiO2 elemental configuration comprises the highest concentration of Si and O. The existence of a siloxane group in the produced compound was revealed by FTIR spectra stretching vibrations at 803.69 and 1089.05 cm-1