Sustainable fabrication of cellulose aerogel embedded with ZnO@noble metal (Ag, Au, Ag-Au) NPs for sensitive and reusable SERS application

Abstract

Nanostructured materials with designable microstructure fabricated through a facile and green method are highly desired for practical applications in nanotechnology. Herein, without using any toxic reagents, flexible cellulose aerogel nanocomposites embedded with ZnO@noble metal nanoparticles (NPs) were successfully prepared from a cellulose dope. Morphology, structure, and mechanical properties of the nanocomposite were characterized. Flower-liker ZnO particles were synthesized through cellulose mineralization and it acted as a platform for efficient photocatalytic synthesis of noble metal (Ag, Au, Ag-Au) NPs. The noble metal NPs were well dispersed in the three-dimensional (3D) cellulose skeleton, resulting in abundant “hot spots” for high Surface Enhanced Raman Scattering (SERS) signal enhancement. Using rhodamine 6 G (R6G) molecules as probe molecules, the detection limits and calculated enhancement factors approached to 10−10 M and 4.8 × 107, respectively. Particularly, the photocatalytic capabilities of noble metal-semiconductor heterostructure embedded in porous aerogel made it a self-cleaned SERS substrate. There was little sensitivity loss after recycling use for 3 times. This work presented a sustainable and cost-reduction strategy to construct sensitive SERS substrate.