Sustainable Coordination Polymer-Based Catalyst and Its Application in the Nitroaromatic Hydrogenation under Mild Conditions.

Abstract

Nitroarene reduction has played a crucial role in the environment remediation and public health. However, few research studies have been undertaken regarding the use of infinite coordination polymer-based catalysts in this process. Herein, we are looking for a way to catalyze the reduction of nitroarenes using a new and well-designed coordination polymer-based palladium catalyst. The Co-BDC-NH2 coordination polymer was prepared through a co-precipitation reaction between 2-amino-1,4-benzenedicarboxylic acid as a linker and the cobalt cation as a node. Functionalization of the prepared Co-BDC-NH2 with 2-pyridinecarboxaldehyde and subsequent metallation with a Pd cation led to the formation of the final catalyst, i.e., Co-BDC-NH2-py-Pd. It has been specified that palladium species substantially contribute to the reduction of nitroarenes in the presence of hydrazine hydrate (N2H4·H2O). The highest conversion (100%) of nitroarenes to the corresponding amines was achieved under relatively mild conditions. This heterogeneous catalyst was able to catalyze the reduction of nitroarenes to desired products without changing other substituents. The reusability and stability of the catalyst were confirmed through four consecutive reduction tests without a major decrease in catalytic activity.