Surroundings effects on the interfacial and temperature behaviors of NaOH/water bound to hydrophilic and hydrophobic nanosilicas

Abstract

HypothesisIt has been assumed that the temperature and interfacial behaviors of concentrated alkali solutions under confined space effects may depend on adsorbent surface structure, hydrophilicity/hydrophobicity, porosity of solids, and dispersion media properties causing kosmotropic or chaotropic effects onto hydrogen bond network (HBN) in bound water and NaOH solution. ExperimentsTo analyze these effects, systems with NaOH/water (0.1 g/g/0.1 g/g) deposited onto compacted hydrophilic (A-300) and hydrophobic (AM1) nanosilicas were studied using 1H NMR spectroscopy (215–287 K). The materials were characterized using several experimental and theoretical methods. FindingsIt has been shown that bound water and water/NaOH represent various clusters and domains whose characteristics depend strongly on nanosilica hydrophilicity/hydrophobicity, dispersion media (air, CDCl3, DMSO, CDCl3/DMSO), subsequent or simultaneous deposition of NaOH and water, and temperature. Water amount (0.1 g/g) was selected too small to completely dissolve NaOH (0.1 g/g) under confined space effects and low temperatures. Chaotropic hydrophobic AM1 and CDCl3 enhance water clusterization and HBN disorder (weakly associated water, WAW appears) in contrast to kosmotropic hydrophilic A-300, NaOH, and DMSO reducing the clusterization and HBN disorder in bound water (WAW disappears). Several aspects related to the interfacial and temperature behaviors of water and co-adsorbates bound to the nanosilicas were elucidated.