Surfactant-assisted hydrothermal fabrication and visible-light-driven photocatalytic degradation of methylene blue over multiple morphological BiVO 4 single-crystallites

Abstract

Monoclinic BiVO 4 single-crystallites with polyhedral, rod-like, tubular, leaf-like, and spherical morphologies have been fabricated using the triblock copolymer P123-assisted hydrothermal strategy with bismuth nitrate and ammonium metavanadate as metal source and various bases as pH adjustor. The physicochemical properties of the materials were characterized by means of the XRD, TGA/DSC, Raman, HRSEM, HRTEM/SAED, XPS, and UV–vis techniques. The photocatalytic activities of the as-fabricated BiVO 4 samples were measured for the photodegradation of methylene blue (MB) under visible-light irradiation. It is shown that factors, such as the pH value of precursor solution, the introduction of surfactant, the nature of alkaline source, and the hydrothermal temperature, have a crucial influence on the particle architecture of the BiVO 4 product. Among the as-fabricated BiVO 4 samples, the ones derived hydrothermally with P123 at pH = 6 or 10 possessed excellent optical absorption performance both in UV- and visible-light regions and hence showed outstanding photocatalytic activities for the addressed reaction. The unusually high visible-light-driven catalytic performance of monoclinically crystallized rod-like and tubular BiVO 4 single-crystallites is associated with the higher surface areas and concentrations of surface oxygen defects, and unique particle morphologies. The possible formation mechanisms of such multiple morphological BiVO 4 materials have also been discussed.