Surfactant-enhanced electrokinetic remediation of polycyclic aromatic hydrocarbons in heterogeneous subsurface environments

Abstract

Polycyclic aromatic hydrocarbon (PAH) contamination exists at numerous sites and poses a substantial risk to public health and the environment. Electrokinetic remediation technology has the potential to treat PAH-contaminated soils, but the effect of soil heterogeneities such as layers, lenses, and mixtures of different soils on the electrokinetic process has not been adequately studied. This study evaluates surfactant-enhanced electrokinetic remediation under heterogeneous soil conditions. A series of bench-scale experiments was conducted using two soils (sand and kaolin) spiked with a representative PAH compound (phenanthrene) in a two-dimensional electrokinetic test apparatus under various layered, lens, or mixed soil configurations. In addition, the homogeneous sand and kaolin soils were each tested alone for comparison purposes. All the experiments employed the same nonionic surfactant (5% Igepal CA-720) flushing solution and a low (0.05) hydraulic gradient. The results showed that the surfactant flushing under the low hydraulic gradient alone was sufficient for complete removal of the contaminant from the homogeneous sand profile, whereas the electroosmotic flow generated by the application of a DC 2.0 V/cm electric potential in a periodic mode considerably enhanced the removal efficiency for the homogeneous and heterogeneous soil profiles containing kaolin. The voltage gradient varied spatially and temporally through the soil profiles and affected the electroosmotic flow and contaminant removal. Key words: clays, electrokinetic remediation, electroosmosis, flushing, heterogeneity, polycyclic aromatic hydrocarbons (PAHs), phenanthrene, soils, sorption, solubilization, surfactants.