Surface-induced nematic and smectic order at a liquid-crystal-silanated-glass interface observed by atomic force spectroscopy and Brewster angle ellipsometry.

Abstract

We have investigated nematic and smectic surface-induced ordering in the isotropic phase of the 4-cyano-4'-n-octylbiphenyl liquid crystal on silanated BK7 and LaSF glass using atomic force spectroscopy and Brewster angle ellipsometry. We have observed complete wetting of the silanated glass surfaces with the nematic phase when approaching the isotropic-nematic phase transition from above. Using the atomic force spectroscopy at the same interfaces, we have detected a significant presmectic ordering that is enhanced at the nematic-isotropic transition. We have observed the first, strongly adsorbed layer of liquid-crystalline molecules underneath this presmectic ordering. This first molecular layer is laterally inhomogeneous with typically 100 nm voids and covers approximately 70% of the surface. It is stable far above the clearing point and is responsible for the surface-memory effect. The results have been analyzed using Landau-de Gennes theory. The surface coupling energies of the nematic and smectic order have been determined, as well as the coupling energy between the nematic and smectic order.