Abstract

The objective of this paper is to highlight the need to combine lifecycle environmental assessment with durability evaluation (tribology and engine tests) to evaluate the potential of surface technologies to contribute to the green deal, in order to make Europe the first climate-neutral continent. Tribology is a scientific discipline that allows one to understand the system reaction to friction and wear. Tribological testing machines are prepared to measure friction at the laboratory level to minimize the wear and heat dissipation of two bodies in relative movement, thus improving the energy efficiency and minimizing CO2 emissions. In this paper, different surface technologies, such as high-velocity oxyfuel (HVOF), physical vapor deposition (PVD), and clean Cr electrolytic processes, are analyzed as promising surface technology solutions from both performance and environmental impact perspectives to replace harmful Cr(VI) coatings. The tribology simulates the working conditions of the real system at the laboratory level, reproducing the failure mechanism and facilitating the laboratory screening of the energy efficiency and durability of materials solutions for certain tribological systems—in this case, engine components. The tribological test results give information about the behavior of materials, while the engine tests gives information about the behavior of components. In this paper, the environmental impact of the production process of the coatings is also analyzed. Two hard chrome processes are compared, demonstrating that by controlling the production process it is possible to significantly reduce the environmental impact of the chrome-plated process, minimizing the environmental impact to that of PVD coatings. The environmental impact of the tested HVOF process is lower than traditional Cr(VI)-plated coatings but higher than PVD coatings. Combining the information from the lifecycle assessment (LCA) and tribological studies, it is possible to assess both the performance and the environmental impact of the surface treatments. This methodology is a tool to that can be used minimize CO2 emissions at the design phase to improve the energy efficiency of products and processes.

Highlights

  • European Union regulations regarding the maximum amount of Cr(VI) content allowable in automotive vehicles are in place

  • This paper presents 2 case studies with the aim of finding alternatives to Cr(VI) coatings, using physical vapor deposition (PVD), high-velocity oxyfuel (HVOF), nitriding treatments and clean electrolytic coatings for cylinder liners or piston rings

  • The aim of this study was to compare the environmental performance of three cylinder liners coated with different coatings; including CrN PVD and 2 hard chromium plating processes: (a) a traditional chrome plating method used before the year 2000 and (b) a second process, called “clean” hard chrome plating introduced by Cromo Duro company in the year 2000

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Summary

Introduction

European Union regulations regarding the maximum amount of Cr(VI) content allowable in automotive vehicles are in place. The aesthetic appearance and good performance of coatings made from this material, in terms of wear and corrosion resistance for different automotive components have made many industries reluctant to introduce new alternatives. In the current EU legislation, the maximum allowable mass of hexavalent chromium is 2 g per vehicle [1]. The hard-chrome-plated components are not part of this legislation (as hard-chrome is Cr(0), in keeping with environmental policy, the exposure. Coatings 2020, 10, 634 of workers to and the environmental load of Cr(VI) during the coating process of hard-chrome on components need to be considered [2,3]. The ReCiPe 2016 methodology was used to quantify the ecological impact of the different coating manufacturing processes. The ReCiPe 2016 methodology was used to quantify the ecological impact of the different coating manufacturing processes. [5]

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