Abstract
Fe–Pt nanoparticles of 3.5 nm in average particle diameter are obtained with the simultaneous chemical reduction of platinum acetylacetonate and the thermal decomposition of iron pentacarbonyl. Because the as-synthesized particles are superparamagnetic at room temperature, they must be transformed to L1 0 ordered phase by annealing at temperatures above 773 K to apply to high-density magnetic recording media. However, the annealing at such high temperatures induces the coalescence and inter-particle sintering. In the present paper, to solve the problem caused by the annealing, we use ultraviolet-ozone treatment to modify particle surface. Even after annealing at 773 K, the crystalline size is kept at 4.4 nm. Furthermore, coercivity is higher than that without the ultraviolet-ozone treatment.
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