Surface topography and microstructure changes of ultrafine-grained graphite prepared from filler of onion-like carbon spheres by Xe ions irradiation

Abstract

Onion-like carbon spheres (OLC) were doped into the traditional graphite raw material system to decrease the pore diameter to ∼400 nm, with potential for use in molten salt reactors. The obtained graphite (OLCG) prepared from OLC was subjected to 7 MeV Xe26+ irradiation in this work, and a systematic investigation was conducted to verify its irradiation behavior. The surface morphology and microstructural evolution in graphite samples under different irradiation conditions were studied with different characterization methods. The surface roughness of OLCG increased and the hill appeared at lower irradiation doses, which was similar to that of IG-110, but the filler particles of OLCG gradually become spherical at 2.5 dpa. The analysis by X-ray diffraction reveals that OLCG's graphitization degree is approaching but slightly worse compared to IG-110. Raman studies indicate that the irradiation causes an increase in defect density and in-plane disorder both in graphite. The OLC filler exhibits a greater sensitivity to radiation, leading to OLCG being slightly sensitive to radiation as compared to IG-110. Neutron irradiation of the resulting graphite should be continued as OLCG showed good irradiation resistance at low irradiation doses and had a much smaller pore diameter.