Surface structure of semicrystalline polyimide films

Abstract

The surface structure of thin films based on poly[4,4′-bis(4″-N-phenoxy)diphenyl]amic acid of 1,3-bis(3′,4-dicarboxyphenoxy)benzene and the product of its thermal imidization—a semicrystalline polyimide—poly[4,4′-bis(4″-N-phenoxy)diphenyl]imide of 1,3-bis(3′,4-dicarboxyphenoxy)benzene—at various stges of thermal imidization and after melting and subsequent annealing has been studied by methods of transmission, scanning electron, and atomic force microscopies. The topological structure of the film surface has been described in terms of the discrete cluster model. Under heating to 200 and 280°C, a continuous network of the infinite cluster appears; subsequent annealing leads to disintegration of the network to discrete fragments that practically correspond to clusters in the starting poly(amic acid) film. The polyimide film heated to 280°C crystallizes in the form of needle crystals stable to the argon plasma. The surface morphology of polyimide films recrystallized from melt is of the spherulite character.