Surface structure of cadmium selenide nanocrystallites

Abstract

Extended x-ray-absorption fine structure ~EXAFS!, Fourier-transform infrared absorption ~FTIR!, and elemental analysis were used on a variety of CdSe nanocrystallites ~NC’s ! to study surface structure. All CdSe NC’s were grown by standard inverse micelle techniques. Two sets of NC’s samples were made. One set was made so that only the size of the NC’s was varied, while the surface treatment was kept the same. The other set was made so that only the surface treatment was varied, while the size distribution was kept the same. For the EXAFS experiments, reference compounds similar in structure were measured. FTIR found surface Cd atoms to be passivated by pyridines and water groups. Fourier-filtered first-shell Cd EXAFS also supports the existence of water groups attached to the surface Cd atoms. The lack of any SeO and Si(CH3) 3 in the FTIR signal indicates that most surface Se atoms have unterminated bonds. Fourier-filtered first-shell Se EXAFS spectra indicate that Se has only Cd as its first-nearest neighbor, and that the coordination number is reduced from the bulk value, suggesting surface Se atoms are unpassivated. Our data support the existence of surface Se lone-pair orbitals that can trap an optically excited hole. @S0163-1829~97!00908-9# Nanocrystallites ~NC’s ! represent a domain of condensed matter that is not well understood. The evolution of physical