Abstract

We use total yield photoelectron spectroscopy to measure the density of occupied states in undoped and lightly boron-doped a-Si:H. We observe a large density of states in the gap of undoped a-Si:H, which we ascribe to near surface defect states. Incorporation of boron removes these states and allows an unobstructed view of the valence band tail. This is shown to be exponential over more than three orders of magnitude in the density of states with an inverse logarithmic slope of 45 meV.

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