Abstract

The surface of a LDPE was modified by Ar, O2, N2, CO2 gaseous plasma. The changes in surface morphology and surface wettability were investigated using AFM and SEM. The surface chemical changes of LDPE were also characterized by FTIR-ATR. The SEM and AFM results demonstrated variable changes in surface roughness for different types of plasma gas used, the changes being more for the Ar and N2 plasma treatments. Considering the nature of the LDPE film, XRD studies were carried out to determine changes in the percentage crystalinity. The results showed that all low pressure O2, Ar, N2, CO2 gas plasmas improved the wettability of LDPE films. Contact angles decreased significantly depending on the discharge powers and exposure times. Surface morphology was also found to vary with plasma discharge powers, exposure times, and the type of gas being used. Ar and N2 gas plasmas in general produced more superior results.

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