Abstract

The surface properties of polycaprolactone (PCL)–poly(ethylene glycol) (PEG) block copolymer (PCE) and blend (B-PCE) of PCL and PEG obviously affect the drug release behavior of the polymer. In this paper, both surface properties of PCE and B-PCE are studied and compared by measuring their water sorption and using the contact angle and X-ray photoelectron spectroscopy technique. The effect of the polyether segment content in PCE and B-PCE on hydrophilicity is discussed. The results show that a hydrophilic polyether segment moves towards the surface and enriches on the surface for either PCE or B-PCE. The enrichment content of the polyether segment of PCE and the hydrophilicity of its surface are higher than that of B-PCE. A reason for the different drug release rates for PCE and B-PCE is suggested.

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