Surface plasmon-like properties of one-dimensional photonic crystal and its application in surface-enhanced fluorescence

Abstract

The present work reports on the plasmon-like properties of one dimensional photonic crystal (1D PhC) as active material for surface-enhanced fluorescence application. 1D PhC was prepared through layer-by-layer deposition of spin coated Poly (methyl methacrylate) and vacuum deposited As2S3. The thicknesses of the alternating layers were tailored with Bragg’s condition for a quarter wave stack. The optical properties of the 1D PhC were characterized by UV-Vis-NIR spectrophotometry. The interaction of surface electromagnetic waves (SEW) supported by the photonic crystals with the localized surface plasmon waves spreading on the surface of very thin metallic films deposited on top of the 1D PhC was investigated. The efficiency of the surface-enhanced fluorescence was studied by using a 0.1 % w/v Cu (II)-phthalocyanine (CuPc) in Pluronic PE 6800 water solution. Two times enhancement of fluorescence signal of CuPc was observed in the case of Au overlayer on the surface of the 1D PhC.