Surface modified and functionalized graphene oxide membranes for separation of strontium from aqueous solutions

Abstract

Graphene oxide-strontium (GO-Sr) composites prepared under different ambient conditions were characterized using morphological and spectroscopic techniques to optimize the uptake of Sr from aqueous solutions. These studies indicated that interactions among GO and Sr2+ ions are highly sensitive to size and aging of GO sheets, as well as pH of the ambience. Further, the extent of Sr uptake on GO sheets was found to be largely influenced by relative fractions of the associated –COOH, –OH, C–O–C functional groups and sp2-C domains. Membranes prepared using various forms of GO were evaluated for their Sr separation ability and, a window of parameters for optimum separation of Sr has been proposed. Among the variety of membranes studied, those made up of fresh and large GO sheets were found to exhibit superior Sr adsorption capacity (~296 mg/g) at limited GO mass. Further, adsorption efficiency of these GO membranes was observed to deteriorate with aging of GO sheets and rise of GO mass on membrane. The membrane based filtration procedure introduced in present work facilitates to provide a lamellar structure of GO sheets with abundant surface area, diverse and accessible sites for Sr2+ ion uptake and offer high Sr adsorption efficiencies.