Abstract

A titanium metal surface was heated with an alkali metal chloride in order to produce a phase transition from amorphous titania to crystalline titania. The anatase-type titania phase was formed by heating the surface with KCl at 550 °C for 3 h. Further heating and higher temperatures caused a transition to the rutile-type titania. The amorphous titania layer on the surface of the titanium metal was reduced with the assistance of alkali metal chloride and reoxidized to transform into the metastable anatase-type titania phase under certain conditions.

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