Abstract

A low-energy Ar+ ion beam was used to modify the surface of a poly(ether imide) (PEI) powder. The modification was promoted by the oxygen gas injected during the irradiation. The surface functional groups of the modified PEI were identified with X-ray photoelectron spectroscopy (XPS). The XPS results show that the bonds originally contained in the imide ring structure are destroyed as a result of random collisions with incident ions and energy transfer to the PEI atoms. Ion-beam irradiated PEI (IBPEI) blends with a thermotropic liquid crystalline polymer (TLCP) show more homogeneous rheological behavior than pristine PEI blends, which is attributed to an interaction between the IBPEI and the TLCP phase. Ion-beam irradiation has a strong effect on the blend morphology, the size of the dispersed phase being remarkably reduced (from 5.3 to 3 μm) and the TLCP phase being finely dispersed. Also, the adhesion between the TLCP phase and the IBPEI is definitely improved. The theoretically calculated interfacial t...

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.