Abstract
Our bond-order-conservation model of surface migration of molecular AB adsorbates [J. Am. Chem. Soc. 106 (1984) 6479] has been generalized to provide for A-B bond-order changes under migration and to search for energy stationary points. The results are rigorous and well defined. The new conclusions corroborate most of the previous findings but also lead to important corrections (e.g., the mogration patterns of donor molecules) and new projections (e.g., monotonic destabilization of AB as its coordination increases without direct relevance to the heat of chemisorption and simple interrelations between molecular and atomic heats of chemisorption), in agreement with experiment.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
