Abstract
Abstract Three kinds of Mo-Ni-Si metallized coatings with various chemical compositions were deposited on SiC ceramic substrates by vacuum fusion sintering process, and the phase compositions of the coatings and their interface microstructures were analyzed. The wetting and spreading properties of molten Ag on the coated SiC ceramic substrates were investigated by the sessile drop technique, and the interfacial behavior of the Ag/coated SiC systems was analyzed. The results show that the coatings are mainly composed of Mo5Si3, MoSi2, Ni2Si, NiSi2 and MoNiSi. The tetragonal MoSi2 grains on the coating surface disappear gradually with the concentration of Mo increasing from 20 at% to 40 at%. The final contact angles of Ag/coated SiC systems at 1000 °C for holding 30 min are 45°, 79° and 85° for the coating compositions of Mo20-Ni32-Si48, Mo30-Ni28-Si42 and Mo40-Ni24-Si36, respectively. This result could be closely related to the interactions between the Ag drop and the microstructures of the three Mo-Ni-Si coatings. No obvious reaction layers are found at all the coating/substrate interfaces before and after the wetting tests.
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