Surface functionalization of porous ZrO 2–TiO 2 membranes using γ-aminopropyltriethoxysilane in palladium electroless deposition

Abstract

A pre-treatment technique was developed to facilitate the electroless deposition of Pd layers onto ZrO 2–TiO 2 ceramic membrane surfaces in the preparation of novel multi-functional porous membranes. Surface functionalization using an aqueous solution of γ-aminopropyltriethoxysilane (γ-APTES) aided the surface immobilization of the Pd activation particles and the subsequent electroless deposition of metal layers onto the hydroxyl-rich membrane surface. The attractiveness of γ-APTES functionalization, in the electroless deposition of metal layers, was thus demonstrated. Characterization techniques employed in the structural study of the surface-modified membranes included SEM, EDS, dynamic analysis in micro-PIXE, and XRD. Special membrane techniques such as electrokinetic analysis and single-gas permeation measurements were also used in the study of surface modification. These membranes were developed for application in tasks associated with the hydrogen economy.