Abstract
AbstractSurface functionalization of porous polymer networks was investigated using the sulfonation of macroporous styrene‐divinylbenzene (S‐DVB) copolymers as model reaction. Reaction conditions for the surface sulfonation were studied. Sulfonation with sulfuric acid in the presence of nitromethane was found to be a suitable method. Models and ideas of network structure are developed in order to estimate surface capacities and to show that surface‐sulfonated networks were obtained.
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