Surface Dilatational Properties and Foam Performance of Surfactant-Nanoparticle Foaming System under Ultra-High Salinity

Abstract

Abstract We have studied the surface dilatational properties of aqueous foaming dispersions containing mixtures of silica nanoparticles (Ludox CL) and sulfobetaine (LHSB) in Tahe formation water. The effects of temperature and pH on the surface dilatational modulus and time shift were studied by oscillating drop module (ODM). The ODM results show that the surface dilatational modulus of mixtures of CL and LHSB is large and increases with the decrease of surface area deformation, which results from hydrophobic interaction between adsorbed mixtures. Under test conditions, the Gibbs stability criterion E > σ/2 against foam coarsening is fulfilled. Results of Brewster angle microscopy (BAM) show that an uniform adsorption layer is established at the air-water interface. Temperature and pH-value influence the dilatation modulus of the surface by hydrophobic interaction or adsorption. Time shift has a similar variation trend. This is a surprising feature. It suggests that LHSB adsorbed on CL can respond to surface tension gradient. The time shift difference results from the response of LHSB at different adsorption sites. In addition, sand pack tests show that compared to LHSB, a finer foam was produced by the mixtures CL/LHSB due to the capillary-induced \snap-off". Thus, higher pressure difference and higher oil recovery could be achieved.