Surface-Confined Light Harvesting, Energy Transfer, and Amplification of Fluorescence Emission in Chromophore-Labeled Self-Assembled Monolayers This research was supported by the office of Naval Research, the AFOSR-MURI program, as well as fellowships from the Netherlands Scientific Organization (NWO), and from the Eastman Kodak Company, which are gratefully acknowledged.

Abstract

Mixtures of derivatives of coumarin-2 and coumarin-343 can self-assemble on silicon wafers to form monolayers in which light harvesting and energy transfer take place (see picture). Photophysical properties, such as donor quenching and fluorescence amplification, were tuned by varying the molar ratio of the donor and acceptor chromophores on the surface or by increasing the number of coumarin-2 chromophores on the donor adsorbate through the use of a dendritic linker. Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2000/z14282_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.