Abstract
Etude realisee en vue de montrer la difference dans le comportement des fers carbonyles dans les zeolites hydratees et deshydratees. Dans le 1er cas le fer carbonyle donne un hydrure anionique HFe 3 (CO) 11 − greffe par interaction ionique avec le cation Al 3+ du reseau de la zeolite d'une facon similaire a celle observee en solution, tandis que les carbonyles sont faiblement adsorbes dans la zeolite deshydratee. Etudes avec les carbonyles modeles: Fe(CO) 5 , Fe 2 (CO) 9 et Fe 3 (CO) 12
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