Abstract

Structural organization and surface acidity of a series of silica-alumina gels covering the range from 100 to 0% SiO 2 have been investigated by photoelectron spectroscopy. No superficial segregation of either SiO 2 or Al 2O 3 is observed and the existence of a distinct alumina phase below 30% SiO 2, as suggested earlier, is further supported by the appearance of an energy-loss peak. Models are presented for the interpretation of the quantitative XPS determination of surface acidity. Close comparison is made between XPS acidity results and those obtained by ir spectroscopy on the same series and a good agreement is observed.

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