Supramolecular solvent-based microextraction of aryl-phosphate flame retardants in indoor dust from houses and education buildings in Spain

Abstract

Aryl-phosphate flame retardants (aryl-OPFRs) are flame retardants or plasticizers (among other functions) that can be found in a wide variety of products, from furniture and textiles to cars and electronic equipment. There is an increasing concern about the human exposure to these contaminants due to their ubiquity (as additives they can be easily released from the product to the environment) and potential toxicity. In this study, we investigated the presence of six representative aryl-OPFRs, two well-known aryl-OPFRs (triphenyl phosphate, TPHP and 2-ethylhexyl diphenyl phosphate, EHDPP), two novel aryl-OPFRs (cresyl diphenyl phosphate, CDP and isodecyl diphenyl phosphate, IDPP) and two oligomeric aryl-OPFRs [bisphenol A bis(diphenyl phosphate), BDP and resorcinol bis(diphenyl phosphate, RDP] in indoor dust from houses and education buildings from Spain. Sample treatment was carried out by a novel and simple procedure based on supramolecular solvents (SUPRAS) prior to LC-MS/MS analysis. The median Σaryl-OPFRs was two times higher in classrooms than in houses, being particularly high at University classrooms. The most abundant aryl-OPFR in houses was TPHP (median 497 ng·g−1) while EHDPP (median 407 ng·g−1) and IDPP (median 403 ng·g−1) were dominant in classrooms. This is the first study reporting IDPP, BDP and RDP in different education buildings.