Supramolecular self-assembled coordination architecture composed of a doubly bis(2-pyridyl)pyrazolate bridged dinuclear CuII complex and 7,7′,8,8′,-tetracyano-p-quinodimethanide radicals

Abstract

A tetranuclear CuII complex composed of a doubly bpypz− bridged dinuclear CuII complex with TCNQ˙− self-assembles into a 3D supramolecular coordination architecture via complementary weak coordination bonding and π-stacking interactions.