Abstract
This Review introduces the research directions for the synthesis of supramolecular fullerene polymers. First, the discovery of host-guest complexes of pristine fullerenes is briefly outlined. We focus on progress in supramolecular fullerene polymers directed by the use of calix[5]arene-fullerene interactions, which comprise linear, networked, helical arrays of fullerenes in supramolecular ensembles. The unique self-sorting behavior of right-handed and left-handed helical supramolecular fullerene arrays is discussed. Thereafter, an extensive investigation of the calix[5]arene-fullerene interaction for control over the chain structures of covalent polymers is introduced.
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