Abstract
Two silver/azide/organodiimine adducts have been isolated and characterized as supramolecular coordination polymers (SCP); [AgN3·L] where L = 4,4′-bipyridine, 1, trans-1,2-bis(4-pyridyl)ethylene, 2. The syntheses were carried out in H2O/CH3CN/NH3 media at room temperature. The topology of the bipodal ligands directs the silver azide building blocks to adopt different 1D-chains as the size and length of the bipodal ligand is increased. The Ag(1) atom in 1 and 2 forms distorted square planar configuration. The emission spectra of 1 and 2 display structural emission peaks at 400–650 nm.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Journal of Inorganic and Organometallic Polymers and Materials
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
