Supramolecular Control of Selectivity in Hydroformylation of Vinyl Arenes: Easy Access to Valuable β‐Aldehyde Intermediates

Abstract

Gegen den Strom! In einem rational entworfenen regioselektiven Hydroformylierungskatalysator, [Rh/L], treten nichtkovalente Ligand-Substrat-Wechselwirkungen auf, die eine ungewöhnliche Selektivitätsumkehrung weg vom α-Aldehyd zum normalerweise nicht gebildeten β-Aldehyd bewirken. Dieses katalytische System eröffnet neuartige und nachhaltige Zugänge zu wichtigen Zwischenstufen der Feinchemikalienindustrie. As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.