Abstract
The dicarboxamide–diphosphine ligand N,N′-bis(2-diphenylphosphinoethyl)phthalamide, dpppa, which is prepared from 2-diphenylphosphinoethylamine and phthaloyl chloride, forms the binuclear gold(I) complex [Au2Cl2(μ-dpppa)], 1, and polymeric complex [{Ag2(μ-O2CCF3)2(μ-dpppa)}n], 2. The ligand and both complexes 1 and 2 undergo further association through hydrogen bonding to give supramolecular polymer or network structures.
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