Supramolecular architectures sustained by arene-C–H…π(quasi-chelate ring) interactions in the crystal structures of copper(I) complexes

Abstract

Abstract A review of the crystallographic literature is presented whereby structures featuring a quasi-six-membered chelate ring of the type {CuCl…HNCS} were evaluated for the presence of intermolecular C–H…π(quasi-chelate) interactions. These are shown to stabilise crystal structures leading to zero-, one-, two- and even three-dimensional architectures. Details of these interactions are described and a comparison to analogous interactions formed intramolecularly has been made. The C–H…π(quasi-chelate) interactions in these structures occur in one-third of structures where such contacts can potentially form.