Suppressive effects of potassium salt modified dry water material on hydrogen/methane mixture explosion

Abstract

As a new type of energy, hydrogen-enriched methane mixed fuel has a high risk of deflagration in the application process. In order to better understand the deflagration and inhibition characteristics of hydrogen-enriched methane fuel, the effect of potassium salt modified dry water material (DW) on the deflagration characteristics of hydrogen-enriched methane fuel was studied by 20 L spherical explosive apparatus, combined with pyrolysis characteristics and kinetic model. The results show that when the addition of different modifier concentrations, it can be divided into three types: small curvature, medium curvature and large curvature according to the change of pressure rising rate. With the increase of the proportion of potassium salt modifiers, the number of areas with small curvature is gradually increasing, the number of large curvature is gradually decreasing, and the number of medium curvature is almost unchanged. When the proportion of potassium salt modifier is 15% and ϕ ≤ 0.7, all enter the area below the medium curvature. When the addition of different modifiers, 15%KCl-DW has the best inhibition effect on Pmax and (dP/dt) max, while CH3COOK-DW and K2CO3-DW have better inhibition effect on Δt2 and Δt2. In general, when the hydrogen addition ratio is less than 70%, the addition of inhibitors can significantly reduce the explosion intensity. In terms of inhibition mechanism, we established the decomposition model of potassium salt modified dry water and found that potassium salt modified dry water will produce a large amount of gaseous K and KOH in the explosion system. And gaseous K and KOH will catalyze each other and combine with H and OH to form stable H2O, which significantly reduces the mass fraction of H and OH radicals in the chain reaction. The results of this paper provide a theoretical basis for the safe use of hydrogen-enriched methane fuel and the research and development of explosion emergency prevention and control technology.